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Fundamentals of Chemistry-II

Book ID: 1826

Author: Dr. Harsha Chatrath

ISBN: 978-93-5016-491-4

About Author

Dr. Mrs.Harsha Chatrath, M.Sc. (Physical Chemistry), PhD, Experience 40 years, Retired Associate Professor and Head of Department of Chemistry, Dr. D.Y. Patil ACS College, Pimpri, Pune. She worked as lecturer and reader at GSCW Jamshedpur (Jharkhand), a constituent of Ranchi University, for 20 Years. She has taught Physical Chemistry, Biotechnology, and Pharmaceutical Physical Chemistry, Agricultural Chemistry, Dairy Chemistry and Environmental Sciences to U.G. and P.G. classes at Ranchi University (Jharkhand) and University of Pune, Pune, Maharashtra, India. Presently she is associated with JJT University, Jhunjhunu (Rajasthan) as Research Guide. She has guided 12 students, of whom 10 students have been awarded Doctorate degree and two more are in progression. She is reviewer and editor of 5 International Journals related to Chemical Sciences. Her topic dissertation was “Heat capacity of rare gases on heterogeneous surfaces.”She has published 35 papers in national and international journals. She has 10 papers on the topics related to Quality Accreditation Accountability and Assessment Process, Motivation and Performance at Higher Education Levels. She has written books for degree level students: (i) Agriculture Chemistry (ii) Dairy Chemistry, (iii) Fundamentals of Chemistry (iv) Physical & Inorganic Chemistry (v) Safety measures in Science Laboratories (vi) Physical Chemistry. She is career counsellor, Pranic healer and Psychotherapist and PLR Therapist. She is member of Indian Science Congress, Indian Association of Chemistry Teachers, Association of College and University Super annuated Teachers. She has received 5 national level awards in appreciation for her work in the field of research and teaching. She has presented many papers on varied subjects at conferences in India and abroad. She is member of RHA (Robin Hood Army) which works for the eradication of hunger and spreading of education amongst slum dwellers.

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Description

Contents

1. Ionic Equilibria
1. pH
2. Buffer
2.1 Action of Buffer Solution
2.2 Mass Law Equation
2.3 Derivation of the Equation
3. Equilibrium Constants
4. Relationship between kc and kp
4.1 Significance of the Magnitude of Equilibrium Constant
4.2 Characteristics of Equilibrium Constant
4.3 Le-Chatelier’s Principle
4.4 Classical Definitions of Acids and Bases
4.5 Arrhenius Theory of Acids and Bases
4.6 Lowry Bronsted Concept
4.7 Conjugate Acid Base Pair
4.8 Amphoteric Nature of Water
4.9 Lewis Concept of Acids and Bases
5. Strong and Weak Acids and Bases
5.1 Degree of Dissociation (?)
5.2 Strength of Acid
5.3 Strength of Base
5.4 Ostwald’s Dilution Law
6. Ionisation of Water
7. Acid Base Titrations
7.1 Neutralization Curves
7.2 Henderson Hasselbalch Equation
8. Solubility Product
8.1 Technical Applications of Solubility Product
8.2 Applications to Analytical Chemistry
8.3 Examples
9. Osmosis
9.1 Osmotic Pressure

2. Chemical Kinetics
1. Introduction
1.1 Types of Reactions
1.2 Rate of Reactions or Reaction Velocity
1.3 Factors Affecting Rate of Reaction or Reaction Velocity
1.4 Law of Mass Action and Rate Law
1.5 Rate Constant and its Significance
2. Molecularity and Order
2.1 Molecularity of Reaction
2.2 Order of Reaction
3. Experimental Methods to Study Rate of Chemical Reactions
4. Terminology of Chemical Kinetics
5. Zero Order Reaction
6. First Order Reaction
6.1 Characteristic of First Order Reaction
6.2 Examples of First order Reactions
7. Second Order Reaction
7.1 Characteristics of Second Order Reaction
7.2 Examples of Second Order Reaction
8. Third Order Reaction
8.1 Characteristics of Third Order Reaction
8.2 Examples of Third Order Reactions
9. Pseudo Molecular Reaction
10. Effect of Temperature on Rate of Reaction
10.1 Derivation of Arrhenius Equation
10.2 Determination of Energy of Activation
11. The Energy of Activation

3. Electrochemistry
1. Introduction
2. Reversible and Irreversible Cells
2.1 Reversible Cells
2.2 Irreversible Cells
3. Electromotive Force (E.M.F.)
3.1 Origin of E.M.F. (Nernst 1889)
3.2 Measurement of E.M.F. (Electromotive Force)
4. Standard Cell
4.1 Cell Reaction and E.M.F.
4.2 Convention Regarding Sign of E.M.F.
5. Single Electrode Potential
5.1 Reference Electrodes
5.2 Determination of Single Electrode Potential
6. Calculation of Cell e.m.f
6.1 Oxidation Potential, Reduction Potential and Electrodes Potential
6.2 Determination of ECell
6.3 Summary of Rules
7. Thermodynamics and E.M.F
8. Liquid Junction Potential
9. Debye-Huckel-Onsagar Equation
10. Over Voltage/Over Potential

4. Basics of Mole Concept
1. Relationship between Molecular Weight and Vapour Density
1.1 Absolute Density
2. Molar Volume or Gram Molecular Volume (GMV)
3. Avogadro’s Number
4. Mole Concept
5. Relationship between Molecular Weight and Vapour Density
5.1 Absolute Density
6. Molecular Weight
7. Modes of Expressing Composition (Concentration) of Solution
8. Ideal Dilute Solution
9. Raoult’s Law