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Fundamental of chemistry-1

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According to New Revised CBCS Syllabus w.e.f. 2019-20

F.Y. Biotechnology

Semesters-I

A Text book of

Fundamentals of Chemistry-I

Author: Dr Harsha Chatrath,Dr Ragunath b. Toche.

ISBN: 978-93-5016-476-1

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In Stock

Contents

1.    Atomic Structure
1.    Introduction
2.    Atomic Models
2.1    Dalton’s Atomic Theory
2.2    The Rutherford Atomic Model
2.3    Bohr Atomic Model
3.    Concept of Atomic and Molecular Orbital
3.1    Molecular Orbital
3.2    Molecular Orbital Theory
3.3    Rules for Filling of Molecular Orbital
2.    Molecules
1.    Introduction
2.    Theory of Bonding
2.1     Valence Bond Theory (V.B.T.)
2.2     Molecular Orbital Theory (M.O.T.) (By Hund and Mullikan)
2.3     Linear Combination of Atomic Orbital (LCAO)
3.    Types of Overlaps
4.    Coulomb's Law of Magnetism
5.    Modern View of Molecular Magnets
1.    Oxygen
2.    Helium molecule ion (He2+)
3.    Nitrogen molecule (N2)
4.    Fluorine molecule (F2)
3.    Chemical Bonding
1.    Chemical Bonding
1.1    Electrovalent or Polar or Ionic Bonds
1.2    Co-valent Bond
2.    Co-ordinate or Dative Bond
3.    Oxidation State or Oxidation Number
3.1    Rules of Oxidation Number
3.2    Oxidation Number and Periodic Table
3.3    Comparison between Valency and Oxidation Number
4.    Oxidation and Reduction
5.    Redox Reaction
5.1    Balance of Redox Equation
5.2    Equivalent Weights of Redox Reagents
4.    Thermodynamics
1.    Chemical Thermodynamics and Energetics
2.    Concept in Thermodynamics
2.1    Energy
2.2    System
2.3    Surrounding
3.    Types of System
4.    Properties of System
5.    Thermodynamic Function or State Function
6.    Types of Processes
7.    Nature of Work and Heat
8.    First Law of Thermodynamics
9.    Enthalpy of a System
10.    Thermochemistry
11.    Thermodynamics
11.1    First Law of Thermodynamics and its Limitations
11.2    Second Law of Thermodynamics
12.    Entropy
12.1     Statements of Second Law of Thermodynamics
12.2    Third Law of Thermodynamics
12.3    Limitations of the Third Law
12.4    Comparison of Third Law with Two Other Laws
12.5    Free Energy Change on Mixing
13.    Gibbs Free Energy (G or F)
13.1    Free Energy Change for Isothermal Conditions
13.2    Significance of Free Energy
13.3    Free Energy Change with Pressure and Temperature
13.4    Free Energy Change with Temperature
13.5    Free Energy Change with Pressure
13.6    An Alternative Equation showing Variation of G with T
13.7    ?G for Chemical Reaction
14.    Bioenergetics
5.    Basics of Organic and Stereochemistry
1.    Nomenclature
1.1    Common Names / Trivial Name
1.2    IUPAC Nomenclature
2.    Reactions of Functional Groups - Alkanes, Alkenes, Alkynes, Alcohol, Amines, Alkyl Halides, Ether
2.1    Alkanes
2.2    Alkenes
2.3    Alkynes
2.4    Alkyl halides Haloalkanes and Haloarenes
2.5    Alcohols
3.    Oxidations, Reductions
3.1    Criteria to decide Oxidation / Reductions in Organic Molecules
3.2    Oxidizing and Reducing Agents
3.3    Examples of Oxidation Reactions4
3.4    Reduction
4.    Elimination
4.1    1, 2-Elimination /-Elimination
5.    Substitution Reactions
5.1    Nucleophilic Aliphatic Substitution (Nucleophilic Substitution Reaction at Saturated Carbon)
6.    Basic of Stereochemistry
6.1    Representation of Molecules
6.2    Conformational Isomerism
6.3    Isomerism
6.4    Optical Isomerism
6.5    Prediction of Number of Possible Stereo Tartaric
6.6    Geometrical or Cis-Trans Isomerism

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